#33: Miley Cyrus and Liam Hemsworth
Liam Hemsworth and Miley Cyrus’s relationship captured much media attention, but it might never have started without an unscripted kiss. While filming The Last Song, the director asked Hemsworth if he was comfortable kissing Cyrus in a scene initially meant to have them wading into the ocean.

Hemsworth agreed without hesitation, and that spontaneous moment marked the beginning of their real-life romance. In a 2010 interview, Hemsworth reflected that the unexpected nature of the kiss worked in his favor, as it left him no time to overthink or get nervous, leading to a genuine and memorable moment.